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S2 E66: All Out Battle! Luffy vs. Zoro, Mysterious Grand Duel!

Luffy, who does not realize the town is full of bounty hunters, engages in a battle with Zoro after he discovers that Zoro attacked the townsfolk, while Mr. 5 and Miss Valentine head for Princess Vivi.

Air date	Apr 22, 2001
Runtime	24 minutes
TMDB rating	★ 7.7/10